NEET-XII-Chemistry
Previous Year Paper year:2017
- #50Which of the following reactions are
disproportionation reaction?
(a )`` 2Cu^+ \longrightarrow`` ``Cu^{2+} + Cu^0``
(b)``3MnO_4^{2-} + 4H^+ \longrightarrow`` ``2MnO_4^- + MnO_2 + 2H_2O``
(c)\begin{aligned}
& \ce{$2KMnO_4 $ ->[\ce{\triangle}] $K_2MnO_4 + MnO_2 + 0_2$}
\end{aligned}
(d)``2MnO_4 ^- + 3Mn^{2+} + 2H_2O \longrightarrow`` ``5MnO_2 + 4H^+``
Select the correct option from the following
(1) (a) and (b) only
(2) (a), (b) and (c)
(3) (a), (c) and (d)
(4) (a) and (d) onlydigAnsr: 1Ans : ( 1 )
Sol. (a)
+
+ 
1
1
2Cu
+
+ +
2 0
2( ) 0
Cu Cu } Disproportionation
(b)
+
ï€ ++ 
6
2( ) ( )
43MnO 4H
+ +
ï€ + +
7 4
4 2 2
2MnO MnO 2H O}Disproportionation
(c)
+ +
â–µï€ ï‚¾ï‚¾ï‚® +
7 6
2
4 2 4
2KMnO K MnO
+
+ ∴
4 0
2 2
MnO O } Not a disproportionation
(d)
+ +
ï€ ++ + 
7 2
2( )
4 22MnO 3Mn 2H O
+
+
4
2
5MnO 4H }
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