NEET-XII-Chemistry

Previous Year Paper year:2017

with Solutions - page 4
  • #50
    Which of the following reactions are
    disproportionation reaction?
    (a )`` 2Cu^+ \longrightarrow`` ``Cu^{2+} + Cu^0``
    (b)``3MnO_4^{2-} + 4H^+ \longrightarrow`` ``2MnO_4^- + MnO_2 + 2H_2O``
    (c)\begin{aligned}
    & \ce{$2KMnO_4 $ ->[\ce{\triangle}] $K_2MnO_4 + MnO_2 + 0_2$}
    \end{aligned}
    (d)``2MnO_4 ^- + 3Mn^{2+} + 2H_2O \longrightarrow`` ``5MnO_2 + 4H^+``
    Select the correct option from the following
    (1) (a) and (b) only
    (2) (a), (b) and (c)
    (3) (a), (c) and (d)
    (4) (a) and (d) only
    digAnsr:   1
    Ans : ( 1 )
    Sol. (a)
    +
    + 
    1
    1
    2Cu
    +
    + +
    2 0
    2( ) 0
    Cu Cu } Disproportionation
    (b)
    +
     ++ 
    6
    2( ) ( )
    43MnO 4H
    + +
     + +
    7 4
    4 2 2
    2MnO MnO 2H O}Disproportionation
    (c)
    + +
    ▵  +
    7 6
    2
    4 2 4
    2KMnO K MnO
    +
    + ∴
    4 0
    2 2
    MnO O } Not a disproportionation
    (d)
    + +
     ++ + 
    7 2
    2( )
    4 22MnO 3Mn 2H O
    +
    +
    4
    2
    5MnO 4H }
    14