NEET-XII-Chemistry
Previous Year Paper year:2017
- #29Machanism of a hypothetical reaction ``\ce X2+ Y2`` → 2XY is given below.
( i) ``X_ 2`` → X + X (fast)
(ii) X + ``Y_2`` ``\rightleftharpoons`` XY + Y (slow)
(iii) X + Y → XY (fast)
The overall order of the reaction will be -
(1) 1.5
(2) 1
(3) 2
(4) 0digAnsr: 1Ans : (1)
Sol. From slow step
r = k [X] [Y2]
but [X] is dummy reactant so it will replaced by step I
]X[
]X[K
2
2
c =
]X[K]X[ 2c=
∴ 122
1
2
2
1
c ]Y[]X[)K(Kr =
so overall order = 5.11
2
1
=+