NEET-XII-Chemistry

Previous Year Paper year:2017

with Solutions - page 2
  • #20
    A 20 litre container at 400 K contains ``CO_2``(g)
    at pressure 0.4 atm and an excess of SrO (neglect the
    volume of solid SrO). The volume of the container is now
    decreased by moving the movable piston fitted in the
    container. The maximum volume of the container, when
    pressure of ``CO_2`` attains its maximum value, will be :
    (Given that : ``SrCO_3``(s) ``\xrightleftharpoons{K}`` SrO (s) + ``CO_2`` ( g),
    ``K_p`` = 1.6 atm)
    (1) 2 litre
    (2) 5 litre
    (3) 10 litre
    (4) 4 litre
    digAnsr:   2
    Ans : (2)
    Sol.
    )s(
    3SrCO )s(
    SrO +
    )g(
    2CO
    At maximum pressure of CO2
    Kp = 2COP = 1.6 atm
    Temperature is constant
    ∴ P1V1 = P2V2
    0.4 × 20 = 1.6 × V2
    V2 = 5 lit