NEET-XII-Chemistry
03: Electrochemistry
- #13Write the chemistry of recharging the lead storage battery, highlighting all the materials that are involved during recharging.
Ans : A lead storage battery consists of a lead anode, a grid of lead packed with lead oxide (PbO2) as the cathode, and a 38% solution of sulphuric acid (H2SO4) as an electrolyte.
When the battery is in use, the following cell reactions take place:
At anode:
At cathode:
The overall cell reaction is given by,

When a battery is charged, the reverse of all these reactions takes place.
Hence, on charging,
present at the anode and cathode is converted into
and
respectively.