NEET-XII-Physics

25: Calorimetry

with Solutions - page 3
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  • #1
    An aluminium vessel of mass 0.5 kg contains 0.2 kg of water at 20°C. A block of iron of mass 0.2 kg at 100°C is gently put into the water. Find the equilibrium temperature of the mixture. Specific heat capacities of aluminium, iron and water are 910 J kg-1 K-1, 470 J kg-1 K-1 and 4200 J kg-1 K-1 respectively.
    Ans : Given:
    Mass of aluminium = 0.5 kg
    Mass of water = 0.2 kg
    Mass of iron = 0.2 kg
    Specific heat of aluminium = 910 J kg-1 K-1
    Specific heat of iron = 470 J kg-1 K-1
    Specific heat of water = 4200 J kg-1 K-1
    Let the equilibrium temperature of the mixture be T.
    Temperature of aluminium and water = 20°C = 273+20 = 293 K
    Temperature of iron = 100°C = 273 + 100 = 373 K
    Heat lost by iron, H1 = 0.2 × 470 × (373 - T)
    Heat gained by water = 0.2 × 4200 × (T - 293)
    Heat gained by iron = 0.5 × 910 × (T-293)
    Total heat gained by water and iron, H2 = 0.5 × 910 (T-293) + 0.2 × 4200 × (T - 293)
    H2 = (T - 293) [0.5 × 910 + 0.2 × 4200]
    We know,
    Heat gain = Heat lost
    ⇒ (T - 293) [0.5 × 910 + 0.2 × 4200] = 0.2 × 470 × (373 -T)
    ⇒ (T - 293) (455 + 840) = 94 (373 - T)
    `` \Rightarrow \left(T-293\right)\frac{1295}{94}=\left(373-T\right)``
    `` \left(T-293\right)\times 14=\left(373-T\right)``
    ⇒ 14 T - 293 × 14 = 373 - T
    ⇒ 15 T = 373 + 4102 = 4475
    `` \Rightarrow T=\frac{4475}{15}=298.33\,\mathrm{\,K\,}\approx 298\,\mathrm{\,K\,}``
    ∴ T = (298 - 273)°C = 25°C
    ∴ Final temperature = 25° C
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