NEET-XII-Chemistry

exam-2 year:2016

with Solutions - page 2
  • #164
    For a sample of perfect gas when its pressure is
    changed isothermally from ``p_i`` to ``p_f``, the
    entropy change is given by
    (1)``\triangle S`` = nRT `` ln \frac {p_f}{p_i}``
    (2)``\triangle S`` = RT `` ln \frac {p_i}{p_f}``
    (3)``\triangle S`` = nR `` ln \frac {p_f}{p_i}``
    (4)``\triangle S`` = nR `` ln \frac {p_i}{p_f}``
    digAnsr:   4
    Ans : (4)
    Sol. ▵ = + 
    f i
    pm
    i f
    T P
    S nC n nR n
    T P
    For isothermal Ti = Tf, ln1 = 0
    ▵ =  i
    f
    P
    S nR n
    P