NEET-XII-Chemistry

exam-2 year:2016

with Solutions - page 2
  • #152
    A given nitrogen-containing aromatic compound A
    reacts with Sn/HCl, followed by ``HNO_2`` to give an
    unstable compound B. B, on treatment with phenol,
    forms a beatiful coloured compound C with the
    molecular formula ``C_{12}H_{10}N_2O``.
    The structure of compound A is :-
    (1)
    (2)
    (3)
    (4)
    digAnsr:   4
    Ans : (4)
    Sol.
    NO2
    (A)
    NH2
    Aniline
    N2·Cl
    
    N N OH
    Sn+HCl
    Reduction
    HNO2
    Ph—OH
    (B)
    Benzene Diazonium
    chloride
    p-Hydroxy azo benzene (red colour dye)