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NEET-XII-Chemistry
exam-1 year:2016
- #49The rate of a f irst -order react ion is
0.04 mol ``l^{-1} s^{-1}`` at 10 seconds and
0.03 mol ``l^{-1} s^{-1}``at 20 seconds after initiation of the
reaction. The half-life period of the reaction is :
(1) 24.1 s
(2) 34.1 s
(3) 44.1 s
(4) 54.1 sdigAnsr: 1Ans : (1)
Sol.
 
 
1
2 1 2
a x2.303
K log
(t t ) a x
ï€
=
ï€ ï€
 
2.303 0.04
K log
20 10 0.03
 
=  
ï€ ïƒ¨ 
2.303 0.1249
K
10
ï‚´
=
ï‚´ ï‚´
=
1/2
2.303 log2 2.303 0.1249
t 10
ï‚´
= =1/2
0.3010 10
t 24.1 sec
0.1249