Loading…
NEET-XII-Chemistry

exam-1 year:2016

with Solutions -
  • #49
    The rate of a f irst -order react ion is
    0.04 mol ``l^{-1} s^{-1}`` at 10 seconds and
    0.03 mol ``l^{-1} s^{-1}``at 20 seconds after initiation of the
    reaction. The half-life period of the reaction is :
    (1) 24.1 s
    (2) 34.1 s
    (3) 44.1 s
    (4) 54.1 s
    digAnsr:   1
    Ans : (1)
    Sol.
     
     
    1
    2 1 2
    a x2.303
    K log
    (t t ) a x
    
    =
     
     
    2.303 0.04
    K log
    20 10 0.03
     
    =  
      
    2.303 0.1249
    K
    10
    ï‚´
    =
    ï‚´ ï‚´
    =
    1/2
    2.303 log2 2.303 0.1249
    t 10
    ï‚´
    = =1/2
    0.3010 10
    t 24.1 sec
    0.1249