NEET-XII-Chemistry

exam-1 year:2016

with Solutions - page 2
  • #64
    The correct thermodynamic conditions for the
    spontaneous reaction at all temperatures is
    (1)``\triangle``H < 0 and ``\triangle``S = 0
    (2) ``\triangle``H > 0 and ``\triangle``S < 0
    (3) ``\triangle``H < 0 and ``\triangle``S > 0
    (4)``\triangle``H < 0 and ``\triangle``S < 0
    digAnsr:   3
    Ans : (3)
    Sol. â–µG = â–µH - T.â–µS
    For, â–µH < 0 and â–µS > 0, â–µG = -ve (always)
    ∴ spontaneous at all temperatures.