Qstnid -Ii-1- Name The Following Halides According To Iupac System And Classify Them As Alkyl, Allyl, Benzyl (Primary, Secondary, Tertiary), Vinyl Or Aryl Halides: () (Ch3)2chch(cl)ch3 () Ch3ch2ch(ch3)ch(c2h5)cl () Ch3ch2c(ch3)2ch2i () (Ch3)3cch2ch(br)c6h5 () Ch3ch=chc(br)(ch3)2 () Ch3ch(ch3)ch(br)ch3 () Ch3c(c2h5)2ch2br () Ch3c(cl)(c2h5)ch2ch3 () Ch3ch=c(cl)ch2ch(ch3)2 () p-clc6h4ch2ch(ch3)2 () m-clch2c6h4ch2c(ch3)3 () o-br-c6h4ch(ch3)ch2ch3 () Ch3ch2ch(ch3)ch(c2h5)cl () Ch3ch2c(ch3)2ch2i () (Ch3)3cch2ch(br)c6h5 () Ch3ch=chc(br)(ch3)2 () Ch3ch(ch3)ch(br)ch3 () Ch3c(c2h5)2ch2br () Ch3c(cl)(c2h5)ch2ch3 () Ch3ch=c(cl)ch2ch(ch3)2 () p-clc6h4ch2ch(ch3)2 () m-clch2c6h4ch2c(ch3)3 () o-br-c6h4ch(ch3)ch2ch3 () Ch3ch2ch(ch3)ch(c2h5)cl () Ch3ch2c(ch3)2ch2i () (Ch3)3cch2ch(br)c6h5 () Ch3ch=chc(br)(ch3)2 () Ch3ch(ch3)ch(br)ch3 () Ch3c(c2h5)2ch2br () Ch3c(cl)(c2h5)ch2ch3 () Ch3ch=c(cl)ch2ch(ch3)2 () p-clc6h4ch2ch(ch3)2 () m-clch2c6h4ch2c(ch3)3 () o-br-c6h4ch(ch3)ch2ch3 () (Ch3)2chch(cl)ch3 () Ch3ch2ch(ch3)ch(c2h5)cl () Ch3ch2c(ch3)2ch2i () (Ch3)3cch2ch(br)c6h5 () Ch3ch=chc(br)(ch3)2 () Ch3ch(ch3)ch(br)ch3 () Ch3c(c2h5)2ch2br () Ch3c(cl)(c2h5)ch2ch3 () Ch3ch=c(cl)ch2ch(ch3)2 () p-clc6h4ch2ch(ch3)2 () m-clch2c6h4ch2c(ch3)3 () o-br-c6h4ch(ch3)ch2ch3 () Ch3ch2ch(ch3)ch(c2h5)cl () Ch3ch2c(ch3)2ch2i () (Ch3)3cch2ch(br)c6h5 () Ch3ch=chc(br)(ch3)2 () Ch3ch(ch3)ch(br)ch3 () Ch3c(c2h5)2ch2br () Ch3c(cl)(c2h5)ch2ch3 () Ch3ch=c(cl)ch2ch(ch3)2 () p-clc6h4ch2ch(ch3)2 () m-clch2c6h4ch2c(ch3)3 () o-br-c6h4ch(ch3)ch2ch3 () Ch3ch2ch(ch3)ch(c2h5)cl () Ch3ch2c(ch3)2ch2i () (Ch3)3cch2ch(br)c6h5 () Ch3ch=chc(br)(ch3)2 () Ch3ch(ch3)ch(br)ch3 () Ch3c(c2h5)2ch2br () Ch3c(cl)(c2h5)ch2ch3 () Ch3ch=c(cl)ch2ch(ch3)2 () p-clc6h4ch2ch(ch3)2 () m-clch2c6h4ch2c(ch3)3 () o-br-c6h4ch(ch3)ch2ch3 - 01: Haloalkanes And Haloarenes

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NEET-XII-Chemistry

01: Haloalkanes and Haloarenes

page 3

Qstn# II-1 Prvs-Qstn Next-Qstn

#1
Name the following halides according to IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
() (CH₃)₂CHCH(Cl)CH₃
() CH₃CH₂CH(CH₃)CH(C₂H₅)Cl
() CH₃CH₂C(CH₃)₂CH₂I
() (CH₃)₃CCH₂CH(Br)C₆H₅
() CH₃CH=CHC(Br)(CH₃)₂
() CH₃CH(CH₃)CH(Br)CH₃
() CH₃C(C₂H₅)₂CH₂Br
() CH₃C(Cl)(C₂H₅)CH₂CH₃
() CH₃CH=C(Cl)CH₂CH(CH₃)₂
() p-ClC₆H₄CH₂CH(CH₃)₂
() m-ClCH₂C₆H₄CH₂C(CH₃)₃
() o-Br-C₆H₄CH(CH₃)CH₂CH₃
() CH₃CH₂CH(CH₃)CH(C₂H₅)Cl
() CH₃CH₂C(CH₃)₂CH₂I
() (CH₃)₃CCH₂CH(Br)C₆H₅
() CH₃CH=CHC(Br)(CH₃)₂
() CH₃CH(CH₃)CH(Br)CH₃
() CH₃C(C₂H₅)₂CH₂Br
() CH₃C(Cl)(C₂H₅)CH₂CH₃
() CH₃CH=C(Cl)CH₂CH(CH₃)₂
() p-ClC₆H₄CH₂CH(CH₃)₂
() m-ClCH₂C₆H₄CH₂C(CH₃)₃
() o-Br-C₆H₄CH(CH₃)CH₂CH₃
() CH₃CH₂CH(CH₃)CH(C₂H₅)Cl
() CH₃CH₂C(CH₃)₂CH₂I
() (CH₃)₃CCH₂CH(Br)C₆H₅
() CH₃CH=CHC(Br)(CH₃)₂
() CH₃CH(CH₃)CH(Br)CH₃
() CH₃C(C₂H₅)₂CH₂Br
() CH₃C(Cl)(C₂H₅)CH₂CH₃
() CH₃CH=C(Cl)CH₂CH(CH₃)₂
() p-ClC₆H₄CH₂CH(CH₃)₂
() m-ClCH₂C₆H₄CH₂C(CH₃)₃
() o-Br-C₆H₄CH(CH₃)CH₂CH₃
() (CH₃)₂CHCH(Cl)CH₃
() CH₃CH₂CH(CH₃)CH(C₂H₅)Cl
() CH₃CH₂C(CH₃)₂CH₂I
() (CH₃)₃CCH₂CH(Br)C₆H₅
() CH₃CH=CHC(Br)(CH₃)₂
() CH₃CH(CH₃)CH(Br)CH₃
() CH₃C(C₂H₅)₂CH₂Br
() CH₃C(Cl)(C₂H₅)CH₂CH₃
() CH₃CH=C(Cl)CH₂CH(CH₃)₂
() p-ClC₆H₄CH₂CH(CH₃)₂
() m-ClCH₂C₆H₄CH₂C(CH₃)₃
() o-Br-C₆H₄CH(CH₃)CH₂CH₃
() CH₃CH₂CH(CH₃)CH(C₂H₅)Cl
() CH₃CH₂C(CH₃)₂CH₂I
() (CH₃)₃CCH₂CH(Br)C₆H₅
() CH₃CH=CHC(Br)(CH₃)₂
() CH₃CH(CH₃)CH(Br)CH₃
() CH₃C(C₂H₅)₂CH₂Br
() CH₃C(Cl)(C₂H₅)CH₂CH₃
() CH₃CH=C(Cl)CH₂CH(CH₃)₂
() p-ClC₆H₄CH₂CH(CH₃)₂
() m-ClCH₂C₆H₄CH₂C(CH₃)₃
() o-Br-C₆H₄CH(CH₃)CH₂CH₃
() CH₃CH₂CH(CH₃)CH(C₂H₅)Cl
() CH₃CH₂C(CH₃)₂CH₂I
() (CH₃)₃CCH₂CH(Br)C₆H₅
() CH₃CH=CHC(Br)(CH₃)₂
() CH₃CH(CH₃)CH(Br)CH₃
() CH₃C(C₂H₅)₂CH₂Br
() CH₃C(Cl)(C₂H₅)CH₂CH₃
() CH₃CH=C(Cl)CH₂CH(CH₃)₂
() p-ClC₆H₄CH₂CH(CH₃)₂
() m-ClCH₂C₆H₄CH₂C(CH₃)₃
() o-Br-C₆H₄CH(CH₃)CH₂CH₃
Ans : null ()

2-Chloro-3-methylbutane

(Secondary alkyl halide)
()

3-Chloro-4-methyhexane

(Secondary alkyl halide)
()

1-Iodo-2, 2 -dimethylbutane

(Primary alkyl halide)
()

1-Bromo-3, 3-dimethyl-1-phenylbutane

(Secondary benzyl halide)
()

4-Bromo-4-methylpent-2-ene

(Allyl halide)
()

2-Bromo-3-methylbutane

(Secondary alkyl halide)
()

1-Bromo-2-ethyl-2-methylbutane

(Primary alkyl halide)
()

3-Chloro-3-methylpentane

(Tertiary alkyl halide)
()

3-Chloro-5-methylhex-2-ene

(Vinyl halide)
()

1-Chloro-4-(2-methylpropyl) benzene

(Aryl halide)
()

1-Chloromethyl-3-(2, 2-dimethylpropyl) benzene

(Primary benzyl halide)
()

1-Bromo-2-(1-methylpropyl) benzene

(Aryl halide)
()

3-Chloro-4-methyhexane

(Secondary alkyl halide)
()

1-Iodo-2, 2 -dimethylbutane

(Primary alkyl halide)
()

1-Bromo-3, 3-dimethyl-1-phenylbutane

(Secondary benzyl halide)
()

4-Bromo-4-methylpent-2-ene

(Allyl halide)
()

2-Bromo-3-methylbutane

(Secondary alkyl halide)
()

1-Bromo-2-ethyl-2-methylbutane

(Primary alkyl halide)
()

3-Chloro-3-methylpentane

(Tertiary alkyl halide)
()

3-Chloro-5-methylhex-2-ene

(Vinyl halide)
()

1-Chloro-4-(2-methylpropyl) benzene

(Aryl halide)
()

1-Chloromethyl-3-(2, 2-dimethylpropyl) benzene

(Primary benzyl halide)
()

1-Bromo-2-(1-methylpropyl) benzene

(Aryl halide)
()

3-Chloro-4-methyhexane

(Secondary alkyl halide)
()

1-Iodo-2, 2 -dimethylbutane

(Primary alkyl halide)
()

1-Bromo-3, 3-dimethyl-1-phenylbutane

(Secondary benzyl halide)
()

4-Bromo-4-methylpent-2-ene

(Allyl halide)
()

2-Bromo-3-methylbutane

(Secondary alkyl halide)
()

1-Bromo-2-ethyl-2-methylbutane

(Primary alkyl halide)
()

3-Chloro-3-methylpentane

(Tertiary alkyl halide)
()

3-Chloro-5-methylhex-2-ene

(Vinyl halide)
()

1-Chloro-4-(2-methylpropyl) benzene

(Aryl halide)
()

1-Chloromethyl-3-(2, 2-dimethylpropyl) benzene

(Primary benzyl halide)
()

1-Bromo-2-(1-methylpropyl) benzene

(Aryl halide)
()

2-Chloro-3-methylbutane

(Secondary alkyl halide)
()

3-Chloro-4-methyhexane

(Secondary alkyl halide)
()

1-Iodo-2, 2 -dimethylbutane

(Primary alkyl halide)
()

1-Bromo-3, 3-dimethyl-1-phenylbutane

(Secondary benzyl halide)
()

4-Bromo-4-methylpent-2-ene

(Allyl halide)
()

2-Bromo-3-methylbutane

(Secondary alkyl halide)
()

1-Bromo-2-ethyl-2-methylbutane

(Primary alkyl halide)
()

3-Chloro-3-methylpentane

(Tertiary alkyl halide)
()

3-Chloro-5-methylhex-2-ene

(Vinyl halide)
()

1-Chloro-4-(2-methylpropyl) benzene

(Aryl halide)
()

1-Chloromethyl-3-(2, 2-dimethylpropyl) benzene

(Primary benzyl halide)
()

1-Bromo-2-(1-methylpropyl) benzene

(Aryl halide)
()

3-Chloro-4-methyhexane

(Secondary alkyl halide)
()

1-Iodo-2, 2 -dimethylbutane

(Primary alkyl halide)
()

1-Bromo-3, 3-dimethyl-1-phenylbutane

(Secondary benzyl halide)
()

4-Bromo-4-methylpent-2-ene

(Allyl halide)
()

2-Bromo-3-methylbutane

(Secondary alkyl halide)
()

1-Bromo-2-ethyl-2-methylbutane

(Primary alkyl halide)
()

3-Chloro-3-methylpentane

(Tertiary alkyl halide)
()

3-Chloro-5-methylhex-2-ene

(Vinyl halide)
()

1-Chloro-4-(2-methylpropyl) benzene

(Aryl halide)
()

1-Chloromethyl-3-(2, 2-dimethylpropyl) benzene

(Primary benzyl halide)
()

1-Bromo-2-(1-methylpropyl) benzene

(Aryl halide)
()

3-Chloro-4-methyhexane

(Secondary alkyl halide)
()

1-Iodo-2, 2 -dimethylbutane

(Primary alkyl halide)
()

1-Bromo-3, 3-dimethyl-1-phenylbutane

(Secondary benzyl halide)
()

4-Bromo-4-methylpent-2-ene

(Allyl halide)
()

2-Bromo-3-methylbutane

(Secondary alkyl halide)
()

1-Bromo-2-ethyl-2-methylbutane

(Primary alkyl halide)
()

3-Chloro-3-methylpentane

(Tertiary alkyl halide)
()

3-Chloro-5-methylhex-2-ene

(Vinyl halide)
()

1-Chloro-4-(2-methylpropyl) benzene

(Aryl halide)
()

1-Chloromethyl-3-(2, 2-dimethylpropyl) benzene

(Primary benzyl halide)
()

1-Bromo-2-(1-methylpropyl) benzene

(Aryl halide)

#1-i
(CH₃)₂CHCH(Cl)CH₃
() CH₃CH₂CH(CH₃)CH(C₂H₅)Cl
() CH₃CH₂C(CH₃)₂CH₂I
() (CH₃)₃CCH₂CH(Br)C₆H₅
() CH₃CH=CHC(Br)(CH₃)₂
() CH₃CH(CH₃)CH(Br)CH₃
() CH₃C(C₂H₅)₂CH₂Br
() CH₃C(Cl)(C₂H₅)CH₂CH₃
() CH₃CH=C(Cl)CH₂CH(CH₃)₂
() p-ClC₆H₄CH₂CH(CH₃)₂
() m-ClCH₂C₆H₄CH₂C(CH₃)₃
() o-Br-C₆H₄CH(CH₃)CH₂CH₃
() CH₃CH₂CH(CH₃)CH(C₂H₅)Cl
() CH₃CH₂C(CH₃)₂CH₂I
() (CH₃)₃CCH₂CH(Br)C₆H₅
() CH₃CH=CHC(Br)(CH₃)₂
() CH₃CH(CH₃)CH(Br)CH₃
() CH₃C(C₂H₅)₂CH₂Br
() CH₃C(Cl)(C₂H₅)CH₂CH₃
() CH₃CH=C(Cl)CH₂CH(CH₃)₂
() p-ClC₆H₄CH₂CH(CH₃)₂
() m-ClCH₂C₆H₄CH₂C(CH₃)₃
() o-Br-C₆H₄CH(CH₃)CH₂CH₃
Ans :

2-Chloro-3-methylbutane

(Secondary alkyl halide)
()

3-Chloro-4-methyhexane

(Secondary alkyl halide)
()

1-Iodo-2, 2 -dimethylbutane

(Primary alkyl halide)
()

1-Bromo-3, 3-dimethyl-1-phenylbutane

(Secondary benzyl halide)
()

4-Bromo-4-methylpent-2-ene

(Allyl halide)
()

2-Bromo-3-methylbutane

(Secondary alkyl halide)
()

1-Bromo-2-ethyl-2-methylbutane

(Primary alkyl halide)
()

3-Chloro-3-methylpentane

(Tertiary alkyl halide)
()

3-Chloro-5-methylhex-2-ene

(Vinyl halide)
()

1-Chloro-4-(2-methylpropyl) benzene

(Aryl halide)
()

1-Chloromethyl-3-(2, 2-dimethylpropyl) benzene

(Primary benzyl halide)
()

1-Bromo-2-(1-methylpropyl) benzene

(Aryl halide)
()

3-Chloro-4-methyhexane

(Secondary alkyl halide)
()

1-Iodo-2, 2 -dimethylbutane

(Primary alkyl halide)
()

1-Bromo-3, 3-dimethyl-1-phenylbutane

(Secondary benzyl halide)
()

4-Bromo-4-methylpent-2-ene

(Allyl halide)
()

2-Bromo-3-methylbutane

(Secondary alkyl halide)
()

1-Bromo-2-ethyl-2-methylbutane

(Primary alkyl halide)
()

3-Chloro-3-methylpentane

(Tertiary alkyl halide)
()

3-Chloro-5-methylhex-2-ene

(Vinyl halide)
()

1-Chloro-4-(2-methylpropyl) benzene

(Aryl halide)
()

1-Chloromethyl-3-(2, 2-dimethylpropyl) benzene

(Primary benzyl halide)
()

1-Bromo-2-(1-methylpropyl) benzene

(Aryl halide)

#1-ii
CH₃CH₂CH(CH₃)CH(C₂H₅)Cl
Ans :

3-Chloro-4-methyhexane

(Secondary alkyl halide)

#1-iii
CH₃CH₂C(CH₃)₂CH₂I
Ans :

1-Iodo-2, 2 -dimethylbutane

(Primary alkyl halide)

#1-iv
(CH₃)₃CCH₂CH(Br)C₆H₅
Ans :

1-Bromo-3, 3-dimethyl-1-phenylbutane

(Secondary benzyl halide)

#1-ix
CH₃CH=CHC(Br)(CH₃)₂
Ans :

4-Bromo-4-methylpent-2-ene

(Allyl halide)

#1-v
CH₃CH(CH₃)CH(Br)CH₃
Ans :

2-Bromo-3-methylbutane

(Secondary alkyl halide)

#1-vi
CH₃C(C₂H₅)₂CH₂Br
Ans :

1-Bromo-2-ethyl-2-methylbutane

(Primary alkyl halide)

#1-vii
CH₃C(Cl)(C₂H₅)CH₂CH₃
Ans :

3-Chloro-3-methylpentane

(Tertiary alkyl halide)

#1-viii
CH₃CH=C(Cl)CH₂CH(CH₃)₂
Ans :

3-Chloro-5-methylhex-2-ene

(Vinyl halide)

#1-x
p-ClC₆H₄CH₂CH(CH₃)₂
Ans :

1-Chloro-4-(2-methylpropyl) benzene

(Aryl halide)

#1-xi
m-ClCH₂C₆H₄CH₂C(CH₃)₃
Ans :

1-Chloromethyl-3-(2, 2-dimethylpropyl) benzene

(Primary benzyl halide)

#1-xii
o-Br-C₆H₄CH(CH₃)CH₂CH₃
Ans :

1-Bromo-2-(1-methylpropyl) benzene

(Aryl halide)