NEET-XII-Chemistry
07: The p-Block Elements
- #19Knowing the electron gain enthalpy values for O → O- and O → O2- as -141
and 702 kJ mol-1 respectively, how can you account for the formation of a
large number of oxides having O2- species and not O-?
(Hint: Consider lattice energy factor in the formation of compounds).
Ans : Stability of an ionic compound depends on its lattice energy. More the lattice energy of a compound, more stable it will be.
Lattice energy is directly proportional to the charge carried by an ion. When a metal combines with oxygen, the lattice energy of the oxide involving O2- ion is much more than the oxide involving O- ion. Hence, the oxide having O2- ions are more stable than oxides having O-. Hence, we can say that formation of O2- is energetically more favourable than formation of O-.